1967:

1. W.S. Trahanovsky and M.P. Doyle, "Thermal Decomposition of t-Butylperoxy 6-bromohexanoate. Lack of Evidence for Radical Displacement on Carbon and 1,5-Bridged Bromine Radicals," J. Org. Chem., 32 , 146-150 (1967).

2. W.S. Trahanovsky, M.P. Doyle, and P.D. Bartlett, "Nucleophilic Reactivity of the Carbon-Carbon Double Bond. VI. The Use of Urea as a Base in Acetolysis Reactions," J. Org. Chem., 32, 150-152 (1967).

3. W.S. Trahanovsky and M.P. Doyle, "Medium Effects. I. Solvolysis of 5-Hexenyl p-Nitrobenzenesulfonate in Acetic Acid - Nonhydroxylic Solvent [20:80] Mixtures," J. Am. Chem. Soc., 89, 4867-4872 (1967).

4. W.S. Trahanovsky and M.P. Doyle, "Failure of the Principle of Hard and Soft Acids and Bases to Explain the Amount of Cyclization of Various 5-Hexenyl Derivatives During Acetolysis," J. Chem. Soc., Chem. Comm., 1021-1022 (1967).

1968:

5. W.S. Trahanovsky and M.P. Doyle, "Medium Effects, II. Cyclization of 6-Heptenyl p-Nitrobenzenesulfonate During Solvolysis in 2,2,2,-Trifluoroethanol," Tetrahedron Lett., 2155-2158 (1968).

6. W.S. Trahanovsky , G.L. Smyser, and M.P. Doyle, "Acetolysis of 4-Bromobutyl-1-d2 p-Nitrobenzenesulfonate. Evidence for 1,4-Bromine Participation and the Existence of a 5-Membered Cyclic Bromonium Ion During Acetolysis," Tetrahedron Lett., 3127-3130 (1968).

1969:

7. W.S. Trahanovsky, M.P. Doyle, P.W. Mullen, and C.C. Ong, "Preparation of Cycloheptanone via a Lewis-Acid Catalyzed Cyclization of 6-Heptenoyl Chloride to b-Chlorocycloheptanone," J. Org. Chem., 34, 3679-3681 (1969).

1970:

8. M.P. Doyle and W. Wierenga, "Reactions of the Nitrosonium Ion. I. The Reaction of Alkyl Azides with Nitrosonium Salts. A New Method for the Production of Carbonium Ions," J. Am. Chem. Soc., 92 , 4999-5001 (1970).

9. M.P. Doyle, R.J. Swedo, and J. Rocek, "Pure Chromium(VI) Oxidations. The Effective Removal of Chromium(IV) from Interference in Oxidations by Chromic Acid," J. Am. Chem. Soc., 92, 7599-7601 (1970).

1972:

10. M.P. Doyle and Wendell Wierenga, "Reactions of the Nitrosonium Ion. II. Reactions of Triphenylmethyl, Benzhydryl, and Benzyl Azides with Nitrosonium Compounds," J. Am. Chem. Soc., 94, 3896-3901 (1972).

11. M.P. Doyle and W. Wierenga, "Reactions of the Nitrosonium Ion. III. Reaction of Alkyl Azides with Nitrosonium Compounds. The Effect of Solvent, Quenching Agent, and Nitrosonium Compound," J. Am. Chem. Soc., 94, 3901-3906 (1972).

12. M.P. Doyle, W. Wierenga, and M.A. Zaleta, "Reactions of the Nitrosonium Ion. IV. Nitrosative Cleavage of the Carbon-Nitrogen Double Bond. The Reaction of N-Arylimines and Ketimines with Nitrosonium Salts," J. Org. Chem., 37, 1597-1601 (1972).

13. M.P. Doyle, D.J. DeBruyn, and D.A. Kooistra, "Silane Reductions in Acidic Media. I. Reduction of Aldehydes and Ketones in Alcoholic Media. A General Synthesis of Ethers," J. Am. Chem. Soc., 94, 3659-3661 (1972).

1973:

14. M.P. Doyle, S. Busman, and J. Majiecko, "The Reaction Between Azide and Nitronium Ions. The Formation and Decomposition of Nitryl Azide," J. Am. Chem. Soc., 95, 952-953 (1973).

15. M.P. Doyle and W.S. Mungall, "A New Approach to Organic Laboratory Projects," J. Chem. Educ., 50, 358 (1973).

16. M.P. Doyle, D.J. DeBruyn and D.J. Scholten, "The Disproportionation of Trityl Alkyl Ethers. The Synthesis of Aldehydes and Ketones in a Cationic Chain Reaction Involving Hydride Transfer," J. Org. Chem., 38 , 625-626 (1973).

17. M.P. Doyle, M.A. Zaleta, J.E. DeBoer, and W. Wierenga, "Reactions of the Nitrosonium Ion. V. Nitrosative Cleavage of the Carbon-Nitrogen Double Bond. The Attempted Exchange of Oxygen for Nitrogen," J. Org. Chem., 38, 1663-1667 (1973).

18. C.T. West, S.J. Donelly, D.A. Kooistra and M.P. Doyle, "Silane Reductions in Acidic Media. II. Reductions of Aryl Aldehydes and Ketones by Trialkylsilanes in Trifluoroacetic Acid. A Selective Method for Converting the Carbonyl Group to Methylene," J. Org. Chem., 38 , 2675-2681 (1973).

19. M.P. Doyle, P.W. Raynolds, R.A. Barents, T.R. Bade, W.C. Danen, and C.T. West, "Free Radical Rearrangements in the Thermal Decomposition of tert-Butylperoxy-3-(1-Phenylcyclopropyl)proponoate, 4-(1-Phenylcyclopropyl)butanoate, and 5-(1-Phenylcyclopropyl)pentanoate," J. Am. Chem. Soc., 95 , 5988-6000 (1973).

20. M.P. Doyle, R.J. Swedo, and J. Rocek, "The Effect of Cerium(III) and Cerium(IV) on Chromic Acid Oxidations. The Elimination of the Chromium(IV) - Alcohol Oxidation," J. Am. Chem. Soc., 95, 8352-8357 (1973).

1974:

21. M.P. Doyle, J.G. Kalmbacher, W. Wierenga, and J.E. DeBoer, "Nitrosative Cleavage of Benzalazine and Related Aldehyde Azines. Production, Decomposition and Trapping of Iminodiazonium Ions," Tetrahedron Lett., 1455-1458 (1974).

22. M.P. Doyle, "A Spectrometric Study of the Oxidation of Alcohols by Cerium(IV)," J. Chem. Educ., 51, 131-132 (1974).

23. M.P. Doyle, D.J. DeBruyn, S.J. Donnelly, D.A. Kooistra, A.A. Odubela, C.T. West, and S.M. Zonnebelt, "Silane Reductions in Acidic Media. III. General Syntheses of Alcohols, Symmetrical Ethers, Carboxylate Esters and Acetamides," J. Org. Chem., 39, 2740 (1974).

1975:

24. M.P. Doyle, G.D. Spoelhof, and M.A. Zaleta, "Reactions of the Nitrosonium Ion. VII. Synthesis of Dihydroisoquinolines and Oxazoles from Azides in Nitrile Solvents," J. Heterocyclic Chem., 12, 263-265 (1975).

25. M.P. Doyle, L.J. Zuidema, and T.R. Bade, "Cyclic Ether Formation in Oxidations of Primary Alcohols by Cerium(IV). Reactions of 5-Phenyl-1-pentanol, 4-Phenyl-1-butanol, and 3-Phenyl-1-propanol with Ceric Ammonium Nitrate," J. Org. Chem., 40, 1454-1456 (1975).

26. M.P. Doyle and C.T. West, "Hindered Organolsilicon Compounds. The Synthesis and Properties of Di-t-butyl-, Di-t -butylmethyl-, and Tri-t-butylsilanes," J. Am. Chem. Soc., 97, 3777-3782 (1975).

27. M.P. Doyle and T.R. Bade, "Internal Lewis Acid Catalyzed Ring-Expansion Reactions of Cyclopropylalkanoyl Chlorides," Tetrahedron Lett., 3031-3034 (1975).

28. M.P. Doyle, D. Hedstrand, S.C. Busman, and D. Alexander, "Reactions of the Nitrosonium Ion. VIII. Reactions of Nitrosonium Tetrafluoroborate and Benzhydryl Tetrafluoroborate with Benzhydryl Azides. The Mechanism of Aldehyde and Ketone Formation," J. Am. Chem. Soc., 97, 5554-5558 (1975).

29. M.P. Doyle, "Reaction Forms Geminal Dihalides" in Chemical & Engineering News, Sept. 8, 1975, pg. 23.

30. M.P. Doyle, J.L. Whitefleet, and M.A. Zaleta, "The Nature of Fluoride Transfer from Complex Fluoride Anions to Carbenium Ions," Tetrahedron Lett., 4201-4204 (1975).

31. M.P. Doyle and C.T. West, "Silane Reductions in Acidic Media. IV. Reductions of Alkyl-Substituted Cyclohexanones by Mono-, Di-, and Trialkylsilanes. Stereochemistry of Alcohol and Ether Formation," J. Org. Chem., 40, 3821-3829 (1975).

32. M.P. Doyle and C.T. West, "Silane Reductions in Acidic Media. V. Reductions of Alkyl-Substituted Cyclohexanones by Di- and Tri- t-butylsilanes. Steric Hindrance to Nucleophilic Attack at Silicon in the Trifluoroacetolysis of Silyl Alkyl Ethers," J. Org. Chem., 40, 3829-3834 (1975).

33. M.P. Doyle and C.T. West, "Silane Reductions in Acidic Media. VI. The Mechanism of Organosilane Reductions of Carbonyl Compounds. Transition State Geometries of Hydride Transfer Reactions," J. Org. Chem., 40, 3835-3838 (1975).

1976:

34. M.P. Doyle and B. Siegfried, "The Disproportionation of Trityl Benzyl Ethers. Kinetic Analysis of the Trityl Salt Catalyzed Reaction. Evidence for the Involvement of Ion Pairs in the Hydrogen Transfer Step," J. Am. Chem. Soc., 98, 163-166 (1976).

35. M.P. Doyle, B. Siegfried, and J.J. Hammond, "Oxidative Deamination of Primary Amines by Copper Halide Nitrosyls. The Formation of Geminal Dihalides," J. Am. Chem. Soc., 98, 1627-1629 (1976).

36. M.P. Doyle and B. Siegfried, "Oxidative Deamination of Primary Amines: Selective Synthesis of Geminal Dihalides," J. Chem. Soc., Chem. Comm., 433-434 (1976).

37. M.P. Doyle, C.C. McOsker, and C.T. West, "Silane Reductions in Acidic Media. VII. Aluminum Chloride Catalyzed Hydrogen-Halogen Exchange Between Organosilanes and Alkyl Halides. An Efficient Hydrocarbon Synthesis," J. Org. Chem., 41, 1393-1396 (1976).

38. M.P. Doyle, C.T. West, S.J. Donnelly, and C.C. McOsker, "Silane Reductions in Acidic Media. VIII. Boron Trifluoride Catalyzed Organosilane Reductions. Selectivity and Mechanisms," J. Organomet. Chem., 117, 129-140 (1976).

1977:

39. M.P. Doyle, J.L. Whitefleet, D.J. DeBruyn, and W. Wierenga, "Decarboxylations of Azodicarboxylates by Nitrosonium and Nitronium Salts. Decarboxylative Oxidation and Substitution Reactions," J. Am. Chem. Soc., 99, 494-498 (1977).

40. M.P. Doyle, C.C. McOsker, N. Ball, and C.T. West, "The Effect of Lewis Acids on Stereoselectivities in Ketone Reductions. The Principle of Complexation-Induced Conformational Perturbation. Energy Minimization in the Transition States for Hydride Transfer," J. Org. Chem., 42, 1922-1928 (1977).

41. M.P. Doyle, B. Siegfried, and J.F. Dellaria, Jr., "Alkyl Nitrite-Metal Halide Deamination Reactions. 2. Substitutive Deamination of Arylamines by Alkyl Nitrites and Copper(II) Halides. A Direct and Remarkably Efficient Conversion of Arylamines to Aryl Halides," J. Org. Chem., 42, 2426-2431 (1977).

42. M.P. Doyle, B. Siegfried, R.C. Elliott, and J.F. Dellaria, Jr., "Alkyl Nitrite-Metal Halide Deamination Reactions. 3. Arylation of Olefinic Compounds in the Deamination of Arylamines by Alkyl Nitrites and Copper(II) Halides. A Convenient and Effective Variation of the Meerwein Arylation Reaction," J. Org. Chem., 42, 2431-2436 (1977).

43. M.P. Doyle, B. Siegfried, and W.F. Fobare, "Nitrosative Oxidation of Arylhydrazines by Alkyl Nitrites and Copper(II) Halides," Tetrahedron Lett., 2655-2658 (1977).

44. M.P. Doyle and D.M. Hedstrand, "Reversible Oxidation of 1,3-Dithiolan-2-thione," J. Chem. Soc., Chem. Comm., 643-644 (1977).

45. M.P. Doyle, J.F. Dellaria, Jr., B. Siegfried, and S.W. Bishop, "Reductive Deamination of Arylamines by Alkyl Nitrites in N,N-Dimethylformamide. A Direct Conversion of Arylamines to Aromatic Hydrocarbons," J. Org. Chem., 42, 3494-3498 (1977).

46. M.P. Doyle, S.B. Williams, and C.C. McOsker, "Boron Trifluoride-Catalyzed Elimination of Borate Esters. A Mild Procedure for the Preparation of Alkenes," Synthesis, 717-718 (1977).

1978:

47. M.P. Doyle and C.C. McOsker, "Silane Reductions in Acidic Media. 10. Ionic Hydrogenation of Cycloalkenes. Stereoselectivity and Mechanism," J. Org. Chem., 43, 693-696 (1978).

48. M.P. Doyle, M. Oppenhuizen, R.C. Elliott, and M.R. Boelkins, "Lewis Acid-Promoted 1,3-Dipolar Addition Reactions of Diazocarbonyl Compounds. A General Synthesis of Oxazoles," Tetrahedron Lett., 2247-2250 (1978).

49. M.P. Doyle, R.J. Bosch, and P.G. Seites, "Alkyl Nitrite-Metal Halide Deamination Reactions. 5. In Situ Generation of Nitrosyl Halides. Effective Product Control from Nitrosyl Chloride Diazotization of Primary Aliphatic Amines in N,N-Dimethylformamide," J. Org. Chem., 43, 4120-4125 (1978).

50. M.P. Doyle, R.C. Elliott, and J.F. Dellaria, Jr., "Lewis Acid - Promoted Reactions of n-(1-Phenylcyclopropyl)alkanoyl Chlorides. Ringsize Effects in Competitive Intramolecular Acylation of Phenyl and Cyclopropyl Substituents," J. Org. Chem., 43, 4459-4461 (1978).

1979:

51. M.P. Doyle and W.J. Bryker, "Alkyl Nitrite-Metal Halide Deamination Reactions. 6. Direct Synthesis of Arenediazonium Tetrafluoroborate Salts from Aromatic Amines, tert-Butyl Nitrite, and Boron Trifluoride Etherate in Anhydrous Media," J. Org. Chem., 44, 1572-1574 (1979).

52. M.P. Doyle, J.L. Whitefleet, and R.J. Bosch, "Reactions of the Nitrosonium Ion. 11. Fluoride Transfer from Complex Fluoride Anions to Carbenium Ions in the Nitrosative Decomposition of Aliphatic Azides," J. Org. Chem., 44, 2923-2929 (1979).

53. M.P. Doyle, W.J. Patrie, and S.B. Williams, "Nickel(II) Bromide - Catalyzed Oxidations of Primary and Secondary Alcohols to Carbonyl Compounds by Benzoyl Peroxide," J. Org. Chem., 44 , 2955-2956 (1979).

54. M.P. Doyle, W.E. Buhro, and J.F. Dellaria, Jr., "Lewis Acid-Promoted Cyclopropanation of a,b -Unsaturated Carbonyl Compounds By Diazocarbonyl Compounds. A Facile Synthesis of 1,2-Disubstituted Cyclopropylcarbonyl Compounds of High Isomeric Purity," Tetrahedron Lett., 4429-4432 (1979).

1980:

55. M.P. Doyle and J.G. Davidson, "Molybdenum Hexacarbonyl Catalyzed Cyclopropanation of a,b -Unsaturated Esters and Nitriles with Diazocarbonyl Compounds," J. Org. Chem., 45, 1538-1539 (1980).

56. M.P. Doyle, M.A. Van Lente, R. Mowat, and W.F. Fobare, "Alkyl Nitrite - Metal Halide Deamination Reactions. 7. Synthetic Coupling of Electrophilic Bromination with Substitutive Deamination for Selective Synthesis of Multiply Brominated Aromatic Compounds from Arylamines," J. Org. Chem., 45, 2570-2575 (1980).

57. M.P. Doyle, R.L. Dow, V. Bagheri, and W.J. Patrie, "Steric Selectivity in Oxidations of Diols," Tetrahedron Lett., 21, 2795-2798 (1980).

58. M.P. Doyle, W.E. Buhro, J.G. Davidson, R.C. Elliott, J.W. Hoekstra, and M. Oppenhuizen, "Lewis Acid Promoted Reactions of Diazocarbonyl Compounds. 3. The Synthesis of Oxazoles from Nitriles Through Intermediate b-Imidatoalkenediazonium Salts," J. Org. Chem., 45, 3657-3664 (1980).

59. M.P. Doyle, F.J. Van Doornik, and C.L. Funkes, "Nitrosyl Transfer to Metalloproteins. Selective Intermolecular Transfer of the Nitrosyl Group from Cobalt Nitrosyls to Hemoglobin and Myoglobin," Inorg. Chim. Acta, 46, L111-L113 (1980).

60. M.P. Doyle and R.L. Dow, "Selective Oxidations of Alcohols by Bromine in Combination with Nickel(II) Benzoate," Synthetic Commun., 10, 881-885 (1980).

1981:

61. M.P. Doyle and J.W. Hoekstra, "Oxidation of Nitrogen Oxides by Bound Dioxygen in Hemoproteins," J. Inorg. Biochem., 14, 351-358 (1981).

62. M.P. Doyle, W.H. Tamblyn, W.E. Buhro, and R.L. Dorow, "Exceptionally Effective Catalysis of Cyclopropanation Reactions by the Hexarhodium Carbonyl Cluster," Tetrahedron Lett., 22 , 1783-1786 (1981).

63. M.P. Doyle, D. van Leusen, and W.H. Tamblyn, "Efficient Alternative Catalysts and Methods for the Synthesis of Cyclopropanes from Olefins and Diazo Compounds," Synthesis, 787-789 (1981).

64. M.P. Doyle, R.A. Pickering, T.M. DeWeert, J.W. Hoekstra, and D.R. Pater, "Kinetics and Mechanism of the Oxidation of Human deoxyHemoglobin by Nitrites," J. Biol. Chem., 256, 12393-12398 (1981).

65. M.P. Doyle, D.M. LePoire, and R.A. Pickering, "Oxidation of Hemoglobin and Myoglobin by Alkyl Nitrites. Inhibition by Oxygen," J. Biol. Chem., 256, 12399-12404 (1981).

66. W.H. Tamblyn, S.R. Hoffman, and M.P. Doyle, "Correlation Between Catalytic Cyclopropanation and Ylide Generation," J. Organomet. Chem., 216, C64-C68 (1981).

67. M.P. Doyle and V. Bagheri, "Regioselective Oxidations of Primary Alcohols in 1,4-Diols," J. Org. Chem., 46 , 4806-4808 (1981).

68. M.P. Doyle, W.H. Tamblyn, and V. Bagheri, "Highly Effective Catalytic Methods for Ylide Generation from Diazo Compounds; Mechanism of the Rhodium and Copper Catalyzed Reactions with Allylic Compounds," J. Org. Chem., 46, 5094-5102 (1981).

69. R.L. Blankespoor, M.P. Doyle, D.M. Hedstrand, W.H. Tamblyn, and D.A. Van Dyke, "Formation and Reactions of Dithiodicarbenium Salts," J. Am. Chem. Soc., 103, 7096-7101 (1981).

70. M.P. Doyle and D. van Leusen, "Transition Metal Catalyzed Rearrangements of Oxocyclopropanes to Vinyl Ethers. Activation by Vicinal Carboalkoxy Substituents," J. Am. Chem. Soc., 103 , 5917-5919 (1981).

1982:

71. M.P. Doyle, R.A. Pickering, R.L. Dykstra, C.L. Nelson, and R.F. Boyer, "Involvement of Peroxide and Superoxide in the Oxidation of Hemoglobin by Nitrite," Biochem. Biophys. Res. Commun., 105, 127-132 (1982).

72. M.P. Doyle, R.A. Pickering, R.L. Dykstra, and B.R. Cook, "Mechanisms of Nitrosyl Transfer. Dissociation of Nitric Oxide from Cobalt Nitrosyls," J. Am. Chem. Soc., 104, 3392-3397 (1982).

73. M.P. Doyle, R.L. Dorow, W.H. Tamblyn, and W.E. Buhro, "Regioselectivity in Catalytic Cyclopropanation Reactions," Tetrahedron Lett., 23, 2261-2264 (1982).

74. M.P. Doyle, R.L. Dorow, and W.H. Tamblyn, "Cyclopropanation of a,b-Unsaturated Carbonyl Compounds and Nitriles with Diazo Compounds. The Nature of the Involvement of Transition Metal Promoters," J. Org. Chem., 47, 4059-4068 (1982).

75. M.P. Doyle and D. van Leusen, "Rearrangements of Oxocyclopropanecarboxylate Esters to Vinyl Ethers. The Disparate Behavior of Transition Metal Catalysts," J. Org. Chem., 47, 5326 (1982).

1983:

76. M.P. Doyle, R.L. Dow, V. Bagheri, and W.J. Patrie, "Regioselectivity in Nickel(II)-Mediated Oxidations of Diols," J. Org. Chem., 48, 476-480 (1983).

77. R.L. Blankespoor, M.P. Doyle, D.J. Smith, D.A. Van Dyke, and M.J. Waldyke, "Chemical and Electrochemical Oxidation of O,O,O-Trisubstituted Phosphorothioates and Triphenylphosphine Sulfide," J. Org. Chem., 48, 1176-1179 (1983).

78. M.P. Doyle, M.R. Colsman, and R.L. Dorow, "Effective Methods for the Syntheses of 2-Pyrazolines and Pyrazoles from Diazocarbonyl Compounds," J. Heterocyclic Chem., 20, 943-946 (1983).

79. M.P. Doyle, R.A. Pickering, and B.R. Cook, "Oxidation of Oxymyoglobin by Nitric Oxide through Dissociation from Cobalt Nitrosyls," J. Inorg. Biochem., 19, 329-338 (1983).

80. M.P. Doyle, J.W. Terpstra, R.A. Pickering, and D.M. LePoire, "Hydrolysis, Nitrosyl Exchange, and Synthesis of Alkyl Nitrites," J. Org. Chem., 48, 3379-3382 (1983).

81. M.P. Doyle and M.L. Trudell, "Homologation of Acetals of a,b-Unsaturated Carbonyl Compounds with Diazoesters. Synthesis of Acetals of b,g -Unsaturated Carbonyl Compounds," J. Org. Chem., 48, 5146-5148 (1983).

1984:

82. M.P. Doyle, R.L. Dorow, W.E. Buhro, J.H. Griffin, W.H. Tamblyn, and M.L. Trudell, "Stereoselectivity of Catalytic Cyclopropanation Reactions. Catalyst Dependence in Reactions of Ethyl Diazoacetate with Alkenes," Organometallics, 3, 44-52 (1984).

83. M.P. Doyle, J.H. Griffin, V. Bagheri, and R.L. Dorow, "Correlations Between Catalytic Reactions of Diazo Compounds and Stoichiometric Reactions of Transition Metal Carbenes with Alkenes. Mechanism of the Cyclopropanation Reaction," Organometallics, 3, 5361 (1984).

84. M.P. Doyle, R.A. Pickering, and J. da Coñceicao, "Structural Effects in Alkyl Nitrite Oxidation of Human Hemoglobin," J. Biol. Chem., 259, 80-87 (1984).

85. M.P. Doyle, J.W. Terpstra, and C.H. Winter, "Nucleophilic Character of an Electrophilic Carbene. Synthesis of Cyclopropanes by Thermal Decomposition of 3-Chloro-3-phenyldiazirine," Tetrahedron Lett., 25, 901-904 (1984).

86. M.P. Doyle and M.L. Trudell, "Catalytic Role of Copper Triflate in Lewis Acid Promoted Reactions of Diazo Compounds," J. Org. Chem., 49, 1196-1199 (1984).

87. M.P. Doyle, S.N. Mahapatro, and S. Van Tran, "Oxidation of Hemoglobin by Arenediazonium Salts. The Influence of Dioxygen," Inorg. Chim. Acta, 92, 123-129 (1984).

88. M.P. Doyle, J.H. Griffin, M.S. Chinn, and D. van Leusen, "Rearrangements of Ylides Generated from Reactions of Diazo Compounds with Allyl Acetals and Thioketals by Catalytic Methods. Heteroatom Acceleration of the [2,3]-Sigmatropic Rearrangement," J. Org. Chem., 49, 1917-1925 (1984).

89. M.P. Doyle, J.W. Terpstra, C.H. Winter, and J.H. Griffin, "Rhodium(II) Acetate Catalyzed Hydrocarbon Oxidations by Molecular Oxygen," J. Molec. Catal., 26, 259-266 (1984).

90. M.P. Doyle and S.N. Mahapatro, "Nitric Oxide Dissociation from Trioxodinitrate(II) in Aqueous Solution," J. Am. Chem. Soc., 106 , 3678-3679 (1984).

91. M.P. Doyle, L.C. Wang, and K.-L. Loh, "Influence of Olefin Coordination on Cyclopropanation Selectivity," Tetrahedron Lett., 25, 4087-4090 (1984).

92. M.P. Doyle, "Research as Chemical Education," J. Chem. Educ., 61, 854-856 (1984).

93. J.M. Nocek, D.M. Kurtz, Jr., R.A. Pickering, and M.P. Doyle, "Oxidation of Deoxyhemerythrin to the Semi-Met Level by Nitrite," J. Biol. Chem., 29, 12334-12338 (1984).

94. M.P. Doyle, M.R. Colsman, and M.S. Chinn, "Olefin Coordination with Rhodium(II) Trifluoroacetate," Inorg. Chem., 23, 3684-3685 (1984).

1985:

95. M.P. Doyle, J.H. Griffin, and J. da Coñceicao, "Procatalysts for Carbenoid Transformations," J. Chem. Soc., Chem. Commun., 328-329 (1985).

96. M.P. Doyle, R.L. Dorow, J.W. Terpstra, and R.A. Rodenhouse, "Synthesis and Catalytic Reactions of Chiral N-Diazoacetyloxazolidones," J. Org. Chem., 50, 1663-1666 (1985).

97. M.P. Doyle, J.G. Herman, and R.L. Dykstra, "Autocatalytic Oxidation of Hemoglobin Induced by Nitrite: Activation and Chemical Inhibition," J. Free Radicals in Biology and Medicine, 1, 145-153 (1985).

98. M.P. Doyle, S.N. Mahapatro, C.M. VanZyl, and M.R. Hester, "Electron Transfer in the Heme Pocket of Hemoglobin," J. Am. Chem. Soc., 107 , 6136-6137 (1985).

1986:

99. M.P. Doyle, K.-L. Loh, L.I. Nishioka, M.B. McVickar, and M.T.H. Liu, "Formation of a Dipolar Adduct in the Reaction of Arylchlorocarbenes with Diethyl Maleate," Tetrahedron Lett., 27, 4395-4398 (1986).

100. M.P. Doyle, "Catalytic Methods for Metal Carbene Transformations," Chem. Rev.(special thematic issue on "Emerging Organic Reactions"), 86, 919-939 (1986).

101. M.P. Doyle, "Electrophilic Metal Carbenes as Reaction Intermediates in Catalytic Reactions," Acc. Chem. Res., 19, 348-356 (1986).

1987:

102. M.P. Doyle, K.-L. Loh, K. DeVries, and M.S. Chinn, "Enhancement of Stereoselectivity in Catalytic Cyclopropanation Reactions," Tetrahedron Lett., 28, 833-836 (1987).

103. M.P. Doyle, J.K. Guy, K.C. Brown, C.M. VanZyl, S.N. Mahapatro, and J.R. Pladziewicz, "Outer-Sphere One-Electron Reductions of Arenediazonium Salts," J. Am. Chem. Soc., 109 , 1536-1540 (1987).

104. M.T.H. Liu, M.P. Doyle, and K.-L. Loh, "Catalysis of Olefin Isomerization by Tight Ion Pairs," J. Org. Chem., 52, 323-324 (1987).

105. M.P. Doyle, A.H. Devia, K.E. Bassett, J.W. Terpstra, and S.N. Mahapatro, "Unsymmetrical Alkenes by Carbene Coupling from Diazirine Decomposition in the Presence of Diazo Compounds," J. Org. Chem., 52 , 1619-1621 (1987).

106. M.P. Doyle, S.N. Mahapatro, A.C. Caughey, M.S. Chinn, M.R. Colsman, N.K. Harn, and A.E. Redwine, "Olefin Coordination with Rhodium(II) Perfluoroalkanoates in Solution," Inorg. Chem., 26, 3070-3072 (1987).

107. M.P. Doyle, S.N. Mahapatro, J.K. Guy, M.R. Hester, C.M. VanZyl, and K.L. Boundy, "Electron Transfer Between Hemoglobin and Arenediazonium Salts. Mechanism of Heme Aryl-Iron Complex Formation," Inorg. Chem., 26, 3387-3392 (1987).

1988:

108. M.P. Doyle, S.N. Mahapatro, R.D. Broene, and J.K. Guy, "Oxidation and Reduction of Hemoproteins by Trioxodinitrate(II). The Role of Nitrosyl Hydride and Nitrite," J. Am. Chem. Soc., 110, 593-599 (1988).

109. M.P. Doyle, M.S. Shanklin, H.Q. Pho, and S.N. Mahapatro, "Rhodium(II) Acetate and Nafion-H Catalyzed Decomposition of N-Aryldiazoamides. An Efficient Synthesis of 2(3H)-Indolinones," J. Org. Chem., 53 , 1017-1022 (1988).

110. M.P. Doyle, M.S. Shanklin, and H.Q. Pho, "Cycloheptatriene Synthesis through Rhodium(II) Acetate-Catalyzed Intramolecular Addition Reactions of N-Benzyldiazoacetamides," Tetrahedron Lett., 29, 2639-2642 (1988).

111. K.C. Brown and M.P. Doyle, "Reduction of Arenediazonium Salts by Hydroquinone. Kinetics and Mechanism for the Electron-Transfer Step," J. Org. Chem., 53, 3255-3261 (1988).

112. M.P. Doyle, M.S. Shanklin, S.-M. Oon, H.Q. Pho, F.R. van der Heide, and W.R. Veal, "Construction of b-Lactams by Highly Selective Intramolecular C-H Insertion from Rhodium(II) Carboxylate Catalyzed Reactions of Diazoacetamides," J. Org. Chem., 53 , 3384-3386 (1988).

113. N. Soundararajan, M.S. Platz, J.E. Jackson, M.P. Doyle, S.-M. Oon, M.T.H. Liu, and S.M. Anand, "Addition of Arylchlorocarbenes to a,b-Unsaturated Esters. Absolute Rates, Substituent Effects, and Variable Reactivities," J. Am. Chem. Soc., 110 , 7143-7152 (1988).

114. M.P. Doyle, V. Bagheri, and N.K. Harn, "Facile Catalytic Methods for Intermolecular Generation of Allylic Oxonium Ylides and their Stereoselective [2,3]-Sigmatropic Rearrangement," Tetrahedron Lett., 29, 5119-5122 (1988).

115. M.P. Doyle, J. Taunton, S.-M. Oon, M.T.H. Liu, N. Soundararajan, M.S. Platz, and J.E. Jackson, "Reactivity and Selectivity in Intermolecular Insertion Reactions of Chlorophenylcarbene," Tetrahedron Lett., 29, 5863-5866 (1988).

116. V. Bagheri, M.P. Doyle, J. Taunton, and E.E. Claxton, "A New and General Synthesis of a-Silyl Carbonyl Compounds by Si-H Insertion from Transition Metal Catalyzed Reactions of Diazo Esters and Diazo Ketones," J. Org. Chem., 53, 6158-6160 (1988).

117. M.P. Doyle, "Tailors, Targets, and Traditions in Undergraduate Research," Forum for Honors, XVIII (No. 4), 6-12 (1988).

1989:

118. J.E. Jackson, N. Soundararajan, M.S. Platz, M.P. Doyle, and M.T.H. Liu, "Activation Parameters for the Reaction of Phenylchlorocarbene with Pyridine, Tri-n-butyltin Hydride, and Triethylsilane: Evidence Against the Need to Invoke Reversibly Formed Complexes in the Reaction of This Carbene with Olefins," Tetrahedron Lett., 30, 1335-1338 (1989).

119. J.R. Pladziewicz and M.P. Doyle, "Application of Marcus Theory to One-Electron Outer-Sphere Electron Transfer Reactions of Benzenediazonium Salts," J. of Imaging Science, 33, 57-61 (1989).

120. M.P. Doyle, Kenneth G. High, S.-M. Oon, and A.K. Osborn, "Diazirines in Carbenoid Reactions Catalyzed by Rhodium(II) Carboxylates," Tetrahedron Lett., 30, 3049-3052 (1989).

121. M.P. Doyle, C.L. Nesloney, M.S. Shanklin, C.A. March, and K.C. Brown, "Formation and Characterization of 3-O-Arenediazoascorbic Acids. New Stable Diazo Ethers," J. Org. Chem., 54, 3785-3789 (1989).

122. M.P. Doyle, J. Taunton, and H.Q. Pho, "Conformational and Electronic Preferences in Rhodium(II) Carboxylate and Rhodium(II) Carboxamide Catalyzed Carbon-Hydrogen Insertion Reactions of N,N-Disubstituted Diazoacetoacetamides," Tetrahedron Lett., 30, 5397-5400 (1989).

123. M.P. Doyle, V. Bagheri, M.M. Pearson, and J.D. Edwards, "Highly Selective g -Lactone Syntheses by Intramolecular Carbenoid Carbon-Hydrogen Insertion in Rhodium(II) Carboxylate and Rhodium(II) Carboxamide Catalyzed Reactions of Diazo Esters," Tetrahedron Lett., 30, 7001-7004 (1989).

1990:

124. M.P. Doyle, V. Bagheri, and E.E. Claxton, "Synthesis of Allenes by [2,3]-Sigmatropic Rearrangement of 2-Propyn-1-yl Oxonium Ylides Formed in Rhodium(II) Carboxylate Catalyzed Reactions of Diazo Compounds," J. Chem. Soc., Chem. Commun., 46-48 (1990).

125. M.P. Doyle, V. Bagheri, T.J. Wandless, N.K. Harn, D.A. Brinker, C.T. Eagle, and K.-L. Loh, "Exceptionally High Trans(anti) Stereoselectivity in Catalytic Cyclopropanation Reactions," J. Am. Chem. Soc., 112, 1906-1912 (1990).

126. P. Müller, N. Pautex, M.P. Doyle, and V. Bagheri, "Rh(II) Catalyzed Isomerizations of Cyclopropenes. Evidence for Rh(II)-complexed vinylcarbene Intermediates," Helv. Chim. Acta, 73, 1233-1241 (1990).

127. H. Brunner, K. Wutz, and M.P. Doyle, "Asymmetrische Katalysen. 58. Enantioselektive S-H- und C-H-Insertionen mit optisch aktiven Rh(II)- und Cu(II)-Katalysatoren," Monatsh. Chem., 121, 755-764 (1990).

128. M.P. Doyle, K.G. High, V. Bagheri, R.J. Pieters, P.J. Lewis, and M.M. Pearson, "Rhodium(II) Perfluorobutyrate Catalyzed Silane Alcoholysis. A Highly Selective Route to Silyl Ethers," J. Org. Chem., 55, 6082-6086 (1990).

129. M.P. Doyle, B.D. Brandes, A.P. Kazala, R.J. Pieters, M.B. Jarstfer, L.M. Watkins, and C.T. Eagle, "Chiral Rhodium(II) Carboxamides. A New Class of Catalysts for Enantioselective Cyclopropanation Reactions," Tetrahedron Lett., 31, 6613-6616 (1990).

1991:

130. M.P. Doyle, R.J. Pieters, J. Taunton, H.Q. Pho, A. Padwa, D.L. Hertzog, and L. Precedo, "Synthesis of Nitrogen Containing Polycycles Via Rhodium(II) Induced Cyclization-Cycloaddition and Insertion Reactions of N-(Diazoacetoacetyl)amides. Conformational Control of Reaction Selectivity," J. Org. Chem., 56, 820-829 (1991).

131. M.P. Doyle, R.J. Pieters, S.F. Martin, R.E. Austin, C.J. Oalmann, and P. Müller, "High Enantioselectivity in the Intramolecular Cyclopropanation of Allyl Diazoacetates Using a Novel Rhodium(II) Catalyst," J. Am. Chem. Soc., 113 , 1423-1424 (1991).

132. M.P. Doyle, K.G. High, C.L. Nesloney, T.W. Clayton, Jr., and J. Lin, "Rhodium(II) Perfluorobutyrate Catalyzed Hydrosilylation of 1-Alkynes. Trans Addition and Rearrangement to Allylsilanes," Organometallics, 10, 1225-1226 (1991).

133. R.C. Smith, J.Z. Gore, and M.P. Doyle, "Degradation of Uric Acid During Autocatalytic Oxidation of Oxyhemoglobin Induced by Sodium Nitrite," Free Radical Biology and Medicine, 11 , 373-377 (1991).

134. M.P. Doyle, "Chiral Catalysts for Enantioselective Carbenoid Cyclopropanation Reactions," Recueil Trav. Chim. Pays-Bas, 110, 305-316 (1991) (review).

135. M.P. Doyle, A. van Oeveren, L.J. Westrum, M.N. Protopopova, and T.W. Clayton, Jr., "Asymmetric Synthesis of Lactones with High Enantioselectivity by Intramolecular Carbon-Hydrogen Insertion of Alkyl Diazoacetates Catalyzed by Chiral Rhodium(II) Carboxamides," J. Am. Chem. Soc., 113, 8982-8984 (1991).

1992:

136. M.P. Doyle, G.A. Devora, A.O. Nefedov, and K.G. High, "Addition/Elimination in the Rhodium(II) Perfluorobutyrate Catalyzed Hydrosilylation of 1-Alkenes. Rhodium Hydride Promoted Isomerization and Hydrogenation," Organometallics, 11 , 549-555 (1992).

137. M.P. Doyle, "The Future of Chemistry Education in the United States," Boletin Soc. Chilena Quim., 37, 251-257 (1992).

138. A. Padwa, D.J. Austin, S.F. Hornbuckle, M.A. Semones, M.P. Doyle, and M.N. Protopopova, "Control of Chemoselectivity in Catalytic Carbenoid Reactions," J. Am. Chem. Soc., 114, 1874-1896 (1992).

139. M.N. Protopopova, M.P. Doyle, P. Müller, and D. Ene, "High Enantioselectivity for Intermolecular Cyclopropenation of Alkynes by Diazo Esters Catalyzed by Chiral Dirhodium(II) Carboxamides," J. Am. Chem. Soc., 114, 2755-2757 (1992).

140. N. McCarthy, M.A. McKervey, T. Ye, M. McCann, E. Murphy, and M.P. Doyle, "Rhodium(II) Binaphthylphosphate - A New Catalyst for Diazocarbonyl Reactions Including Asymmetric Synthesis," Tetrahedron Lett., 33, 5983-5986 (1992).

141. M.P. Doyle, M.N. Protopopova, W.R. Winchester, and K.L. Daniel, "Enantiocontrol and Regiocontrol in Lactam Syntheses by Intramolecular Carbon-Hydrogen Insertion Reactions of Diazoacetamides Catalyzed by Chiral Rhodium(II) Carboxamides," Tetrahedron Lett., 33, 7819-7822 (1992).

142. M.P. Doyle, M.Y. Eismont, D.E. Bergbreiter, and H.N. Gray, "Enantioselective Metal Carbene Transformations with Polyethylene-Bound Soluble Recoverable Dirhodium(II) 2-Pyrrolidone-5(S)-carboxylate," J. Org. Chem., 57, 6103-6105 (1992).

1993:

143. M.P. Doyle, L.J. Westrum, W.N.E. Wolthuis, M.M. See, W.P. Boone, V. Bagheri, and M.M. Pearson, "Electronic and Steric Control in Carbon-Hydrogen Insertion Reactions of Diazoacetoacetates Catalyzed by Dirhodium(II) Carboxylates and Carboxamides," J. Am. Chem. Soc., 115, 958-964 (1993).

144. M.P. Doyle and M.S. Shanklin, "Highly Efficient Regioselective Silylcarbonylation of Alkynes Catalyzed by Dirhodium(II) Perfluoroborate," Organometallics, 12, 11-12 (1993).

145. M.P. Doyle, M.N. Protopopova, B.D. Brandes, H.M.L. Davies, N.J.S. Huby, and J.K. Whitesell, "Diastereoselectivity Enhancement in Cyclopropanation and Cyclopropenation Reactions of Chiral Diazoacetate Esters Catalyzed by Chiral Dirhodium(II) Carboxamides," Synlett, 151-153 (1993).

146. M.P. Doyle, L.J. Westrum, M.N. Protopopova, M.Y. Eismont, and M.B. Jarstfer, "Dirhodium(II) Tetraacetate Catalyzed Hydroboration of Alkenes," Mendeleev Communications, 81-82 (1993).

147. M.P. Doyle and B.F. Plummer, "Replacing Mineral Acids in the Laboratory. Nafion® NR50 Catalyzed Dehydration and Esterification Reactions," J. Chem. Educ., 70, 493-495 (1993).

148. A. Padwa, D.J. Austin, A.T. Price, M.A. Semones, M.P. Doyle, M.N. Protopopova, W.R. Winchester, and A. Tran, "Ligand Effects on Dirhodium(II)-Carbene Reactivities. Highly Effective Switching Between Competitive Carbenoid Transformations," J. Am. Chem. Soc., 115, 8669-8680 (1993).

149. M.P. Doyle, W.R. Winchester, J.A.A. Hoorn, V. Lynch, S.H. Simonsen, and R. Ghosh, "Dirhodium(II) Tetrakis(carboxamidates) with Chiral Ligands. Structure and Selectivity in Catalytic Metal Carbene Transformations," J. Am. Chem. Soc., 115, 9968-9978 (1993).

150. M.P. Doyle, S.-M. Oon, F. van der Heide, and C.B. Brown, "b -Lactam Formation via Rhodium(II) Catalyzed Carbon-Hydrogen Insertion Reactions of a-Diazo Amides," Bioorganic and Medicinal Chemistry Letters(Symposium-in-Print, Invited Contribution), 3, 2409-2414 (1993).

151. M.P. Doyle, W.R. Winchester, M.N. Protopopova, P. Müller, G. Bernardinelli, D. Ene, and S. Motallebi, "Dirhodium(II) Tetrakis[4(S)-phenyloxazolidinone] and its Catalytic Applications for Metal Carbene Transformations," Helv. Chim. Acta, 76, 2227-2235 (1993).

1994:

152. M.P. Doyle and M.S. Shanklin, "Highly Regioselective and Stereoselective Silylcarbonylation of Alkynes Under Mild Conditions Promoted by Dirhodium(II) Perfluorobutyrate," Organometallics, 13, 1081-1088 (1994).

153. M.P. Doyle, M.Y. Eismont, M.N. Protopopova, and M.M.Y. Kwan, "Enantioselective Intramolecular Cyclopropanation of N-Allylic- and N-Homoallylic Diazoacetamides Catalyzed by Chiral Dirhodium(II) Catalysts," Tetrahedron (Symposium-in-Print, Invited Contribution), 50, 4519-4528 (1994).

154. M.P. Doyle, A.B. Dyatkin, G.H.P. Roos, F. Cañas, D.A. Pierson, A. van Basten, P. Müller, P. Polleux, "Diastereocontrol for Highly Enantioselective Carbon-Hydrogen Insertion Reactions," J. Am. Chem. Soc., 116 , 4507-4508 (1994).

155. M.P. Doyle, A.B. Dyatkin, and J.S. Tedrow, "Synthesis of 2-Deoxyxylolactone from Glycerol Derivatives via Highly Enantioselective Carbon-Hydrogen Insertion Reactions," Tetrahedron Letters, 35, 3853-3856 (1994).

156. M.P. Doyle, W.R. Winchester, S.H. Simonsen, and R. Ghosh, "Dirhodium(II) Tetrakis[ N,N-dimethyl-2-pyrrolidone-5(S)-carboxamide]. Structural Effects on Enantioselection in Metal Carbene Transformations," Inorg. Chim. Acta (Symposium-in-Print, Invited Contribution), 220, 193-196 (1994).

157. M.P. Doyle, M.S. Shanklin, and M.V. Zlokazov, "Regioselective Hydroformylation of Alkenes Catalyzed by Di(m-carboxylato)rhodium(I) Complexes," Synlett, 615-616 (1994).

158. M.P. Doyle, M.N. Protopopova, P. Müller, D. Ene, and E.A. Shapiro, "Effective Uses of Dirhodium(II) Tetrakis[methyl 2-pyrrolidone-5(R or S)-carboxylate] for Highly Enantioselective Intramolecular Cyclopropanation Reactions," J. Am. Chem. Soc., 116, 8492-8498 (1994).

159. T. Ye, M.A. McKervey, B.D. Brandes, and M.P. Doyle, "Stereoselective Synthesis of Disubstituted 3(2H)-Furanones via Catalytic Intramolecular C-H Insertion Reactions of a-Diazo-b-keto Esters Including Asymmetric Induction," Tetrahedron Lett., 35, 7269-7272 (1994).

160. G.A. Devora and M.P. Doyle, "Highly Efficient Olefin Isomerization Catalyzed by Metal Hydrides Derived from Dirhodium(II) Carboxylates and Catecholborane," Main Group Metal Chemistry, 7, 395-398 (1994). (Special issue for undergraduate research.)

161. M.P. Doyle, "Highly Enantioselective Syntheses from Diazocarbonyl Compounds Catalyzed by Chiral Dirhodium(II) Carboxamides," Chemica Oggi (Chemistry Today), Nov./Dec. issue, 12, 13-20 (1994) (invited review).

162. M.P. Doyle, "Asymmetric Syntheses with Catalytic Enantioselective Metal Carbene Transformations," Russian Chemical Bulletin (Izvestiya Akademii Nauk., Ser. Khim.), 43, 1770-1782 (1994) (invited review).

1995:

163. M.P. Doyle, A.B. Dyatkin, and C.L. Autry, "A New Catalytic Transformation of Diazo Esters. Hydride Abstraction in Dirhodium(II) Catalyzed Reactions," J. Chem. Soc., Perkin Trans. 1, 619-621 (1995).

164. P. Müller, C. Baud, D. Ene, S. Motallebi, M.P. Doyle, B.D. Brandes, A.B. Dyatkin, and M.M. See, "Enantio- and cis/trans-Selectivity in Dirhodium(II)-Catalyzed Addition of Diazoacetates to Olefins," Helv. Chim. Acta, 78 , 459 (1995).

165. M.P. Doyle, A.B. Dyatkin, M.N. Protopopova, C.I. Yang, C.S. Miertschin, W.R. Winchester, S.H. Simonsen, V. Lynch, and R. Ghosh, "Enhanced Enantiocontrol in Catalytic Metal Carbene Transformations with Dirhodium(II) Tetrakis[methyl 2-oxazolidinone-4( )-carboxylate], Rh₂(4S-MEOX)₄,"Recueil Trav. Chim. Pays-Bas (Chirality Issue, Invited Contribution), 114, 163-170 (1995).

166. M.P. Doyle, R.E. Austin, A.S. Bailey, M.P. Dwyer, A.B. Dyatkin, A.V. Kalinin, M.M.Y. Kwan, S. Liras, C.J. Oalmann, R.J. Pieters, M.N. Protopopova, C.E. Raab, G.H.P. Roos, Q.-L. Zhou, and S.F. Martin, "Enantioselective Intramolecular Cyclopropanations of Allylic and Homoallylic Diazoacetates and Diazoacetamides Using Chiral Dirhodium(II) Carboxamide Catalysts," J. Am. Chem. Soc., 117 , 5763-5775 (1995).

167. M.P. Doyle and A.B. Dyatkin, "Spirolactones from Dirhodium(II)-Catalyzed Diazodecomposition with Regioselective Carbon-Hydrogen Insertion," J. Org. Chem., 60, 3035-3038 (1995).

168. M.P. Doyle, M.N. Protopopova, C.D. Poulter, and D.H. Rogers, "Macrocyclic Lactones from Dirhodium(II) Catalyzed Intramolecular Cyclopropanation and Carbon-Hydrogen Insertion," J. Am. Chem. Soc., 117, 7281-7282 (1995).

169. M.P. Doyle, Q.-L. Zhou, C.E. Raab, and G.H.P. Roos, "Improved Enantioselection for Chiral Dirhodium(II) Carboxamide-Catalyzed Carbon-Hydrogen Insertion Reactions of Tertiary Alkyl Diazoacetates," Tetrahedron Lett., 36, 4745-4748 (1995).

170. M.P. Doyle and Q.-L. Zhou, "Enantioselective Catalytic Intramolecular Cyclopropanation of Allylic a-Diazopropionates Optimized with Dirhodium(II) Tetrakis[methyl 2-oxazolidinone-4(S or R)-carboxylate]," Tetrahedron: Asymmetry, 6, 2157-2160 (1995).

171. M.P. Doyle, A.B. Dyatkin, A.V. Kalinin, D.A. Ruppar, S.F. Martin, M.R. Spallar, S. Liras, "Highly Selective Enantiomer Differentiation in Intramolecular Cyclopropanation Reactions of Racemic Secondary Allylic Diazoacetates," J. Am. Chem. Soc., 117, 11021-11022 (1995).

172. M.P. Doyle and A.V. Kalinin, "Highly Enantioselective Route to b -Lactams via Intramolecular C-H Insertion Reactions of Diazoacetylazacycloalkanes Catalyzed by Chiral Dirhodium(II) Carboxamidates," Synlett, 1075-1076 (1995).

173. M.P. Doyle and A.V. Kalinin, "Enantiomer Differentiation in Intramolecular Carbon-Hydrogen Insertion Reactions of Racemic Secondary Alkyl Diazoacetates Catalyzed by Chiral Dirhodium(II) Carboxamidates," Russ. Chem. Bull., 44 , 1729-1734 (1995).

174. M.P. Doyle, Q.-L. Zhou, A.B. Dyatkin, and D.A. Ruppar, "Enhancement of Enantiocontrol/Diastereocontrol in Catalytic Intramolecular Cyclopropanation and Carbon-Hydrogen Insertion Reactions of Diazoacetates with Rh₂(4S-MPPIM)₄ ," Tetrahedron Lett., 36, 7579-7582 (1995).

175. M.P. Doyle, M.N. Protopopova, Q.-L. Zhou, J.W. Bode, S.H. Simonsen, and V. Lynch, "Optimization of Enantiocontrol for Carbon-Hydrogen Insertion with Chiral Dirhodium(II) Carboxamidates. Synthesis of Natural Dibenzylbutyrolactone Lignans from 3-Aryl-1-propyl Diazoacetates in High Optical Purity," J. Org. Chem., 60, 6654-6655 (1995).

1996:

176. M.P. Doyle, W.R. Winchester, M.N. Protopopova, A.P. Kazala, and L.J. Westrum, "(1R,2S)-(-)-6,6-Dimethyl-3-oxabicyclo[3.1.0]hexan-2-one. Highly Enantioselective Intramolecular Cyclopropanation Catalyzed by Dirhodium(II) Tetrakis[methyl 2-Pyrrolidone-5(R)-Carboxylate}," Organic Synthesis (invited procedure), 73, 13-24 (1996).

177. M.P. Doyle and A. V. Kalinin, "Synthesis of Pyrrolizidine Bases by Highly Diastereoselective and Regioselective Catalytic Carbon-Hydrogen Insertion Reactions of Chiral Pyrrolidinediazoacetamides," Tetrahedron Lett., 37, 1371-1374 (1996).

178. M.P. Doyle and A.V. Kalinin, "Highly Enantioselective Intramolecular Cyclopropanation Reactions of N-Allylic-N-methyldiazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxamidates," J. Org. Chem., 61, 2179-2184 (1996).

179. M.P. Doyle, "Chiral Dirhodium Carboxamidates. Catalysts for Highly Enantioselective Syntheses of Lactones and Lactams," Aldrichimica Acta, 29 (No. 1), 3-11 (1996).

180. M.P. Doyle, C.S. Peterson, and D.L. Parker, Jr., "Formation of Macrocyclic Lactones by Enantioselective Intramolecular Cyclopropanation of Diazoacetates Catalyzed by Chiral Copper(I) and Rhodium(II) Compounds,"Angew. Chem. Int. Ed. Engl., 35, 1334-1336 (1996); Angew. Chem., 108, 1439-1440 (1996).

181. M.P. Doyle, Q.-L. Zhou, C. Charnsangavej, M.A. Longoria, M.A. McKervey, and C.F. Garcia, "Chiral Catalysts for Enantioselective Intermolecular Cyclopropanation Reactions with Methyl Phenyldiazoacetate. Origin of the Solvent Effect in Reactions Catalyzed by Homochiral Dirhodium(II) Prolinates," Tetrahedron Lett., 37, 4129-4132 (1996).

182. M.P. Doyle, Q.-L. Zhou, S.H. Simonsen, and V. Lynch, "Dirhodium(II) Tetrakis[alkyl 2-oxaazetidine-4( S)-carboxylates]. A New Set of Effective Chiral Catalysts for Asymmetric Intermolecular Cyclopropanation Reactions with Diazoacetates," Synlett, 697-698 (1996).

183. M.P. Doyle, M.N. Protopopova, C.S. Peterson, J.P. Vitale, M.A. McKervey, and C.F. Garcia, "Formation of Macrocycles by Catalytic Intramolecular Aromatic Cycloaddition of Metal Carbenes to Remote Arenes," J. Am. Chem. Soc., 118 , 7865-7866 (1996).

184. M.P. Doyle, Q.-L. Zhou, C.E. Raab, G.H.P. Roos, S.H. Simonsen, and V. Lynch, "Synthesis and Structures of (2,2-cis)-Dirhodium(II) Tetrakis[methyl 1-acyl-2-oxoimidazolidin-4( S)-carboxylates]. Chiral Catalysts for Highly Stereoselective Metal Carbene Transformations," Inorg. Chem., 35, 6064-6073 (1996).

185. M.P. Doyle, A.V. Kalinin, and D.G. Ene, "Chiral Catalyst Controlled Diastereoselection and Regioselection in Intramolecular Carbon-Hydrogen Insertion Reactions of Diazoacetates," J. Am. Chem. Soc., 118, 8837-8846 (1996).

186. R.T. Buck, M.P. Doyle, M.J. Drysdale, L. Ferris, D.C. Forbes, D. Haigh, C.J. Moody, N.D. Pearson, and Q.-L. Zhou, "Asymmetric Rhodium Carbenoid Insertion into the Si-H Bond," Tetrahedron Lett., 37, 7631-7634 (1996).

187. J.W. Bode, M.P. Doyle, M.N. Protopopova, and Q.-L. Zhou, "Intramolecular Regioselective Insertion into Unactivated Prochiral Carbon-Hydrogen Bonds with Diazoacetates Catalyzed by Chiral Dirhodium(II) Carboxamidates. Highly Enantioselective Total Synthesis of Natural Lignan Lactones," J. Org. Chem., 61 , 9146-9155 (1996).

1997:

188. M.P. Doyle, C.S. Peterson, Q.-L. Zhou, and H. Nishiyama, "Comparative Evaluation of Enantiocontrol for Intramolecular Cyclopropanation of Diazoacetates with Chiral Cu(I), Rh(II), and Ru(II) Catalysts," J. Chem. Soc., Chem. Commun., 211-212 (1997).

189. M.P. Doyle, C.E. Raab, G.H.P. Roos, V. Lynch, and S.H. Simonsen, "(4,0)-Dirhodium(II) Tetrakis[methyl 1-acetyl-2-oxoimidazolidin-4(S)-carboxylate]. Implications for the Mechanism of Ligand Exchange Reactions," Inorg. Chim. Acta, 266, 13-18 (1997).

190. M.P. Doyle and M.A. McKervey, "Recent Advances in Enantioselective Syntheses Involving Diazocarbonyl Intermediates," J. Chem. Soc., Chem. Commun., 983-989 (1997) (Feature Article).

191. M.P. Doyle, M.E. Eismont, and Q.-L. Zhou, "Enantiocontrol in Intramolecular Cyclopropanation of Diazo Ketones. Conformational Control of Metal Carbene Alignment," Russ. Chem. Bull., 46, 955-958 (1997).

192. H. Brunner, C. Blüchel, and M.P. Doyle, "Copper Catalysts with Optically Active Ligands in the Enantioselective Meerwein Arylation of Activated Olefins," J. Organomet. Chem., 541, 89-95 (1997).

193. M.P. Doyle, D.G. Ene, D.C. Forbes, and J.S. Tedrow, "Highly Enantioselective Oxonium Ylide Formation and Stevens Rearrangement Catalyzed by Chiral Dirhodium(II) Carboxamidates," Tetrahedron Lett., 38, 4367-4370 (1997).

194. M.P. Doyle and C.S. Peterson, "Macrocyclic Oxonium Ylide Formation and Internal [2,3]-Sigmatropic Rearrangement. Catalyst Influence on Selectivity," Tetrahedron Lett., 38, 5265-5268 (1997).

195. M.P. Doyle, D.C. Forbes, M.N. Protopopova, S.A. Stanley, M.M. Vasbinder, and K.R. Xavier, "Stereocontrol in Intermolecular Dirhodium(II) Catalyzed Carbonyl Ylide Formation and Reactions. Dioxolanes and Dihydrofurans," J. Org. Chem., 62, 7210-7215 (1997).

196. M.P. Doyle, C.S. Peterson, M.N. Protopopova, A.B. Marnett, D.L. Parker, Jr., D.G. Ene, and V. Lynch, "Macrocycle Formation by Catalytic Intramolecular Cyclopropanation. A New General Methodology for the Synthesis of Macrolides," J. Am. Chem. Soc., 119, 8826-8837 (1997).

1998:

197. G.H.P. Roos, C.E. Raab, N.D. Emslie, M.P. Doyle, and V. Lynch, "Synthesis, Structure, and Reactivity of a Novel Series of Diastereomeric Dirhodium(II) Tetracarboxamidates. Catalysts for Asymmetric Diazoacetate Transformations," Aust. J. Chem., 51, 1-8 (1998).

198. M.P. Doyle and D.C. Forbes, "Recent Advances in Asymmetric Catalytic Metal Carbene Transformations," Chem. Rev., 98, 911-935 (1998) (invited review).

199. D.C. Forbes, D.G. Ene, and M.P. Doyle, "Stereoselective Synthesis of Substituted 5-Hydroxy-1,3-dioxanes," Synthesis, 879-882 (1998).

200. M.P. Doyle, D.C. Forbes, and K.R. Xavier, "Dirhodium(II) Catalyzed Carbonyl Ylide Generation. Stereoelectronic Control in Dioxolane Formation," Russ. Chem. Bull., 47, 932-935 (1998).

201. M.P. Doyle, D.C. Forbes, M.M. Vasbinder, and C.S. Peterson, "Enantiocontrol in the Generation and Diastereoselective Reactions of Oxonium Ylides Catalyzed by Chiral Dirhodium(II) Carboxamidates. Metal-Stabilized Ylides as Reaction Intermediates," J. Am. Chem. Soc., 120, 7653-7654 (1998).

202. M.P. Doyle and M.N Protopopova, "New Aspects of Catalytic Asymmetric Cyclopropanation," Tetrahedron, 54, 7919-7946 (1998).

203. M.P. Doyle, "New Catalysts and Methods for Highly Enantioselective Metal Carbene Reactions," Pure Appl. Chem., 70, 1123 (1998).

1999:

204. M.P. Doyle, D.G. Ene, C.S. Peterson, and V. Lynch, "Macrocyclic Cyclopropenes by Highly Enantioselective Intramolecular Addition of Metal Carbenes to Alkynes," Angew. Chem. Int. Ed. Engl., 38, 722-724 (1999).

205. M.P. Doyle, "Enantiocontrol in Catalytic Metal Carbene Reactions," Russ. Chem. Bull., 48, 16-20 (1999) (invited review).

206. M.P. Doyle, D.G. Ene, D.C. Forbes, and T.H. Pillow, "Chemoselectivity and Enantiocontrol in Catalytic Intramolecular Metal Carbene Reactions of Diazoacetates Linked to Reactive Functional Groups by Naphthalene-1,8-dimethanol," J. Chem. Soc., Chem. Commun., 1691-1692 (1999).

207. M.P. Doyle, B.J. Chapman, W. Hu, and C.S. Peterson, "Catalytic Intramolecular Addition of Metal Carbenes to Remote Furans," Org. Lett., 1 , 1327-1329 (1999).

208. M.P. Doyle, "Control of Enantioselectivity in Catalytic Metal Carbene Reactions," Enantiomer, 4, 621-632 (1999) (invited review).

209. M.P. Doyle, J.S. Tedrow, A.B. Dyatkin, C.J. Spaans, and D.G. Ene, "Enantioselective Synthesis of 2-Deoxyxylono-1,4- lactone and 2-Deoxyribono-1,4- lactone from 1,3- Dioxan-5-yl Diazoacetates," J. Org. Chem., 64, 8907-8915 (1999).

2000:

210. M. P. Doyle, S. B. Davies, and W. Hu, "Dirhodium(II) Tetrakis[methyl 2-oxaazetidine-4-carboxylate]: A Chiral Dirhodium(II) Carboxamidate of Exceptional Reactivity and Selectivity," Organic Lett., 2, 1145-1147 (2000).

211. M. P. Doyle, S. B. Davies, and W. Hu, "Optimization of Enantiocontrol in cis-Selective Cyclopropanation Reactions Catalyzed by Dirhodium(II) Tetrakis-[alkyl 2-oxaazetidine-4(S)-carboxylates]," J. Chem. Soc.,Chem. Commun., 867-868 (2000).

212. M. P. Doyle, W. Hu, B. Chapman, A. B. Marnett, C. S. Peterson, J. P. Vitale, and S. A. Stanley, "Enantiocontrolled Macrocycle Formation by Catalytic Intromolecular Cyclopropanation," J. Am. Chem. Soc., 122, 5718 (2000).

213. M. P. Doyle, W. Hu, I. M. Phillips and Andrew G. H. Wee "A New Approach to Macrocyclization via Alkene Formation in Catalytic Diazo Decomposition. Synthesis of Patulolides A and B," Org. Lett., 2 (12), 1777-1779 (2000).

214. M. P. Doyle, W. Hu "Reactivities and Selectivities in Macrocyclic Addition Reactions with Diazoacetates using Copper(I) and Rhodium(II) Catalysts," Tetrahedron Lett., 41, 6265-6269 (2000).

215. M. P. Doyle, W. Hu, "Selectivity in Reactions of Allyl Diazoacetates as a Function of Catalyst and Ring Size from g-Lactones to Macrocyclic Lactones," J. Org. Chem., 65, 26, 8839-8847 (Dec. 29, 2000 cover art).
 

2001:

216. M. P. Doyle, W. Hu, "Enantiocontrol in Macrocycle Formation from Catalytic Metal Carbene Transformations," Chinese J. of Chem., 19, 1, 22-29 (2001) (review).

217. D. J. Timmons, M. P. Doyle, "Catalyst Selection for Metal Carbene Transformations," J. Organometallic Chem., 617-618, 94-194 (2001) (invited review).

218. M. P. Doyle, W. Hu, I. M. Phillips, C. J. Moody, and A. G. Pepper, "Reactivity Enhancement for Chiral Dirhodium(II) Tetrakis(Carboxamidates)," Adv. Synth. & Cat., 343, 1, 112-117 (2001).

219. M. P. Doyle, W. Hu, and D. J. Timmons "Epoxides and Aziridines from Diazoacetates via Ylide Intermediates," Org. Lett., 3, 933-935 (2001).

220. M. P. Doyle and I. M. Phillips, "Cyclopropanation versus Carbon-Hydrogen Insertion.  The Influences of Substrate and Catalyst on Selectivity," Tetrahedron Lett., 42, 3155-3158 (2001).

221. M. P. Doyle and W. Hu "A New Enantioselective Synthesis of Milnacipran and an Analog by Catalytic Asymmetric Cyclopropanation," Adv. Synth. & Cat., 343, 299-302 (2001).

222. M. P. Doyle, I. M. Phillips, and W. Hu, "A New Class of Chiral Lewis Acid Catalysts for Highly Enantioselective Hetero-Diels-Alder Reactions: Exceptionally High Turnover Numbers from Dirhodium(II) Carboxamidates," J. Am. Chem. Soc., 123, 5366-5367 (2001).

223. M. P. Doyle and E. J. May "Enantioselective b -Lactone Formation from Phenyldiazoacetates via Catalytic Intramolecular Carbon-Hydrogen Insertion," Synlett, 967-969 (2001) (special issue honoring R. Noyori).

224. M. P. Doyle and W. Hu, "Macrocycle Formation from Catalytic Metal Carbene Transformations," Synlett, 1364-1370 (2001) (invited review).

225. M. P. Doyle, S. B. Davies, and E. J. May, "High Selectivity from Configurational Match/Mismatch in Carbon-Hydrogen Insertion Reactions of Steroidal Diazoacetates Catalyzed by Chiral Dirhodium(II) Carboxamidates," J. Org. Chem.,66, 8112-8119 (2001).

226. M. P. Doyle, W. Hu, D. J. Timmons, "Highly Stereoselective Syntheses of Five- and Seven-Membered Ring Heterocycles from Ylides Generated by Catalytic Reactions of Styryldiazoacetates with Aldehydes and Imines," Org. Lett., 3, 3741-3744 (2001).

227. M. P. Doyle, D.J. Timmons, M.R.M. Arndt, A. Duursma, J. T. Colyer, and H. Brunner, "First Attempts at Differential Diastereoselection in Catalytic Reactions of Dirhodium(II) Tetrakis-[Methyl N-(chiral attachment)-2-oxamidazolidine-4( S)-carboxylates] with Diazoacetates," Russ. Chem. Bull.,50, in press (2002) (special issue honoring O. Nefedov).

228. M. P. Doyle and M. Yan, "Effective and Highly Stereoselective Coupling with Vinyldiazomethanes to Form Symmetrical Trienes," J. Org. Chem.66, 602-604 (2001).