Link to FULL PUBLICATIONS list

RECENT PUBLICATIONS

L. Zhou, B.N. Timmermann, C. Grittini, M.A. Bruck and J.H. Enemark, "Tarapacol 15-acetate, a New Diterpenoid from Grindelia tarapacana Phil," Acta. Crystallogr., C52, 1042-1044 (1996).

I.K. Dhawan and J.H. Enemark, "EPR Studies of Oxo-Mo(V) Complexes with Sulfur Donor Ligands: Implications for the Molybdenum Center of Sulfite Oxidase," Inorg. Chem., 35, 4873-4882 (1996).

Z. Xiao, M.A. Bruck, J.H. Enemark, C.G. Young and A.G. Wedd, "A Catalytic Cycle Related to Molybdenum Enzymes Containing [Mo^VIO₂]²⁺ Oxidized Active Sites," Inorg. Chem., 35, 7508-7515 (1996).

Z. Xiao, M.A. Bruck, J.H. Enemark, C.G. Young and A.G. Wedd, "Trimethylsilyloxo Complexes of Oxomolybdenum(V). Coupled Electron-Electrophile Reactions," J. Bio. Inorg. Chem. 1, 415-423 (1996).

A. Pacheco, P. Basu, P. Borbat, A.M. Raitsimring and J.H. Enemark, "Multifrequency ESEEM Spectroscopy of Sulfite Oxidase in Phosphate Buffer: Direct Evidence for Coordinated Phosphate," Inorg. Chem., 35, 7001-7008 (1996).

K.R. Barnard, M. Bruck, S. Huber, C. Grittini, J.H. Enemark, R.W. Gable and A.G. Wedd, "Mononuclear and Binuclear Mo(V) Complexes of the Ligand N,N-bis(2-mercaptophenyl)ethylenediamine: Geometric Isomers," Inorg. Chem., 36, 637-749 (1997).

P. Basu, A.M. Raitsimring, J.H. Enemark and F.A. Walker, "Oxomolybdenum(V)/-Iron(III) Porphyrinate Complexes: The Effect of Axial Ligand Plane Orientation on Complex Stability, Reduction Potential, NMR and EPR Spectra," Inorg. Chem., 36, 1088-1094 (1997).

P. Basu and J.H. Enemark, "A Paramagnetic Complex Possessing Two Oxo-Mo(V) Centers," Inorg. Chim. Acta, 263/1-2, 81-85 (1997).

M.H. Wall, Jr., P. Basu, T. Buranda, B.S. Wicks, E.W. Findsen, M. Ondrias, J.H. Enemark and M.L. Kirk, "Photoinduced Electron Transfer in Covalently Linked Oxo-Molybdenum(V) Porphyrin Systems," Inorg. Chem., 36, 5676-5677 (1997).

B.L. Westcott and J.H. Enemark, "Formal Oxidation States vs. -Effects in Isostructural Low-Symmetry [MoNO]³⁺ and [MoO]³⁺ Complexes: A Photoelectron Spectroscopy Study.," Inorg. Chem., 36, 5404-5405 (1997). .

A.A. Holder, T.P. Dasgupta, W. McFarlane, N.H. Rees, J.H. Enemark, A. Pacheco and K. Christensen, "Syntheses, Characterization, Infrared and ⁹⁵Mo NMR Spectroscopy of Some Coordinated Oxo-Molybdenum(VI) Complexes," Inorg. Chim. Acta, 260, 225-228 (1997).

J.H. Enemark and C.D. Garner, "The Coordination Chemistry and Function of the Molybdenum Centres of the Oxomolybdoenzymes," JBIC, J. Biol. Inorg. Chem.,2, 817-822 (1997).

C. Kisker, H. Schindelin, A. Pacheco, W. Wehbi, R.M. Garrett, K.V. Rajagopalan, J.H. Enemark and D.C. Rees, "Molecular Basis of Sulfite Oxidase Deficiency from the Structure of Sulfite Oxidase," Cell, 91, 973-983 (1997).

B.L. Westcott, N.E. Gruhn, and J.H. Enemark, "Evaluation of Molybdenum-Sulfur Interactions in Molybdoenzyme Model Complexes by Gas-Phase Photoelectron Spectroscopy. The "Electronic Buffer" Effect," J. Am. Chem. Soc., 120, 3382-3386 (1998).

J.H. Enemark, "EPR and MCD Studies of Oxomolybdenum Centers in Sulfite Oxidase and Related Model Compounds," in Spectrocopic Methods in Bioinorganic Chemistry; ACS Symposium Series 692, Solomon, E.I.; Hodgson, K.O., Eds; Ch 21; pp 360-371 (1998). ( invited contribution)

C.J. Rawn, D.P. Birnie, III, M.A. Bruck, J.H. Enemark, and R.S. Roth, "Structural Investigation of Ba6-3xLn8+2xTi18O54 (x = 0.27, Ln = Sm) by Single Crystal X-ray Diffraction in Space Group Pnma (No. 62)," J. Mater. Res., 13, 187-196 (1998).

J. McMaster and J.H. Enemark, "The Active Sites of Mo- and W-Containing Enzymes," Curr. Opin. in Chem. Biol., 2, 201-207 (1998).

J.H. Enemark and B.L. Westcott, "Transition Metal Nitrosyls" in Inorganic Electronic Structure and Spectroscopy; A.B.P. Lever and E.I. Solomon, Eds., Wiley, invited chapter, in press.

P. Basu and J.H. Enemark, "Binuclear Oxo Molybdenum-Metalloporphyrinato Complexes," in Inorganic Synthesis, Vol. 33, D. Coucouvanis, Ed., in press.

B. Fischer, J.H. Enemark, and P. Basu, "A Chemical Approach to Systematically Designate the Pyranopterin Center of Molybdenum and Tungsten Enzymes and Synthetic Models," J. Inorg. Biochem., accepted.

A.M. Raitsimring, A. Pacheco, and J.H. Enemark, "ESEEM Investigations of the High pH and Low pH Forms of Chicken Liver Sulfite Oxidase," J. Am. Chem. Soc. , submitted 6/98.

A. Pacheco, J.T. Hazzard, G. Tollin and J.H. Enemark, "The pH Dependence of Intramolecular Electron Transfer Rates in Sulfite Oxidase at High and Low Anion Concentrations," J. Am. Chem. Soc., submitted 6/98.