Microwave Spectra and Structures of Organometallic Compounds

12/9/98

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Table of Contents

PPT Slide

Microwave Spectra and Structures of Organometallic Compounds

Outline

Structural Determinations

Organometallics

Previous Studies

Present Studies

PPT Slide

Microwave Studies

Microwave Spectra ? Molecular Structure

Iron Tetracarbonyl Dihydride

Metal Hydrides

Dihydride Structures

M - H Anharmonicity and 2nd order isotope effects

H - M - H Bending Potential DFT - BPW91

Ethylene Iron Tetracarbonyl

Microwave Spectrum of EtFe(CO)4 “R”- Branch J = 2 ? 3

Structure of C2H4Fe(CO)4

Structural Changes in Ethylene Upon Complexation to Iron

Allyl Iron Tricarbonyl Bromide

Piano Stool and Sandwich Compounds

Cyclopentadienyl Indium/Thallium

Quadrupole Coupling in Indium

Chloroferrocene and Bromoferrocene

Hyperfine Structure of 35Cl-ferrocene

Comparison of C-Cl bonding in Chlorobenzene and Chloroferrocene

Methyl Rhenium TriOxide (MTO)

Quadrupole Coupling in CpRe(CO)3

Quadrupole Coupling in Re Compounds

CpRh(CO)2 a V10 Hindered Rotor

Trithiacyclonane - S3C6H12

Conformational Analysis of Trithiacyclononane

Conformational Analysis of Trithiacyclononane

Summary

Acknowledgements

Author: SGK 

Email: bdrouin@u.arizona.edu

Home Page: http://www.chem.arizona.edu/~drouinb/index.html