UPSTutorial

Contents

1. Title slide.
   
   
2. Photoelectric effect.
   
   
3. Instrumentation.
   
   
4. Photon sources.
   
   
5. REMPI and ZEKE.
   
   
6. Sample requirements.
   
   
7. Applications.
   
   
8. Facility.
   
   
9. Importance of PES
   
   
10. Orbital ordering and PES.
    
    
11. Why ionization energies?
    
    
12. Simple hydrogen molecule.
    
    
13. Conservation of energy.
    
    
14. Positive ion states.
    
    
15. Large molecules.
    
    
16. Ionization assignments.
    
    
17. Vibrational structure.
    
    
18. Distortion analysis.
    
    
19. Potential well description.
    
    
20. Localized M-H bond.
    
    
21. Electron transfer.
    
    
22. Inner-shell reorganization energy.
    
    
23. Oligoacenes example.
    
    
24. Reorganization energy analysis.
    
    
25. Visual trends in reorganization energy.
    
    
26. Band shape information.
    
    
27. Thermodynamic cycle
    
    
28. Relation to bond energy.
    
    
29. PES of Mo(CO)5L Complexes .
    
    
30. Molecule series.
    
    
31. Piano stool MOs.
    
    
32. Mp, FpH, and FpCl.
    
    
33. Pi stabilization with FpCN
    
    
34. Metal-metal complexes.
    
    
35. Metal-metal d orbital interactions.
    
    
36. Metal-metal symmetry combinations.
    
    
37. Widely tunable metal-metal systems.
    
    
38. Factors affecting ionizatoin energies.
    
    
39. Dimetal tetraacetates.
    
    
40. Mo2 vibrational fine structure.
    
    
41. Potential well illustration.
    
    
42. Effect of changing metal.
    
    
43. Effect of charge distribution.
    
    
44. Ligand substitutions.
    
    
45. Correlation with electrochemistry.
    
    
46. Solvent effects.
    
    
47. Why photoelectron spectroscopy?
    
    
48. Photoelectron spectroscopists.
    
    
49. A nice place to do research.
    
    

Comments or Questions?

Last updated:
February 09, 2004 (Monday)